One-pot oxidation and protonation of a bridging sulfide and rare crystallographic evidence of a coordinated [SO] complex in [Pt2(μ-S2O2H)(PPh3)4]+
Literature Information
Jingqiu Li, Lip Lin Koh, T. S. Andy Hor
One-pot oxidation and protonation of the sulfide bridging complex [Pt2(μ-S)2(PPh3)4] can be promoted by lanthanide or scandium compounds, leading to the isolation of [Pt2(μ-S2O2H)(PPh3)4]+; crystallographic elucidation confirmed sulfide mono-oxygenation without S–S bonding to give formally [SO]2− in the form of an [SOHOS]3− overhead bridge.
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