One-pot oxidation and protonation of a bridging sulfide and rare crystallographic evidence of a coordinated [SO] complex in [Pt2(μ-S2O2H)(PPh3)4]+

Literature Information

Publication Date 2009-04-29
DOI 10.1039/B902625H
Impact Factor 6.222
Authors

Jingqiu Li, Lip Lin Koh, T. S. Andy Hor


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Abstract

One-pot oxidation and protonation of the sulfide bridging complex [Pt2(μ-S)2(PPh3)4] can be promoted by lanthanide or scandium compounds, leading to the isolation of [Pt2(μ-S2O2H)(PPh3)4]+; crystallographic elucidation confirmed sulfide mono-oxygenation without S–S bonding to give formally [SO]2− in the form of an [SOHOS]3− overhead bridge.

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Front cover

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DOI: 10.1039/C3CP90035E

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