Solvatomagnetic effect and spin-glass behavior in a 1D coordination polymer constructed from EE-azido bridged MnIII3O units

Literature Information

Publication Date 2007-11-12
DOI 10.1039/B715080F
Impact Factor 6.222
Authors

Cai-Ming Liu, De-Qing Zhang, Dao-Ben Zhu


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Abstract

The non-uniform chain manganese(III) complex constructed from EE-azido bridged MnIII3O units, [MnIII3O(Brppz)3(MeOH)3(N3)]·2MeOH [1, Brppz = 3-(5-bromo-2-phenolate)pyrazolate], is the first example of 1D azido-bridged coordination polymer showing both solvatomagnetic effect and spin-glass behavior.

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