Unprecedented carbon–carbon bond formation induced by photoactivation of a platinum(iv)-diazido complex
Literature Information
Luca Ronconi
UVA-induced photodecomposition of a PtIV-diazido complex involves not only reduction to PtII and N2 release, but also O2 evolution and formation of nitrene intermediates, whose trapping with (CH3)2S gives rise to an unusual N,N′-bis(ethyl)sulfurousdiamide ligand in an apparently unprecedented process involving C–C bond formation.
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