Unprecedented carbon–carbon bond formation induced by photoactivation of a platinum(iv)-diazido complex
Literature Information
Publication Date
2007-10-23
DOI
10.1039/B714216A
Impact Factor
6.222
Authors
Luca Ronconi
View Original
Abstract
UVA-induced photodecomposition of a PtIV-diazido complex involves not only reduction to PtII and N2 release, but also O2 evolution and formation of nitrene intermediates, whose trapping with (CH3)2S gives rise to an unusual N,N′-bis(ethyl)sulfurousdiamide ligand in an apparently unprecedented process involving C–C bond formation.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
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2458
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Recommended Compounds
Tert-butyl 3-iodo-5-nitro-1H-indazole-1-carboxylate
CAS Number:
459133-69-8
Molecular Formula:
C12H12IN3O4
![Imidazo[1,2-c]pyrimidine structure](https://static.chemtradehub.com/structs/274/274-78-2-8b4c.webp "Imidazo[1,2-c]pyrimidine structure")
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