Tetravalent cerium carbene complexes

Literature Information

Publication Date 2007-10-09
DOI 10.1039/B713041D
Impact Factor 6.222
Authors

Ian J. Casely, Stephen T. Liddle, Alexander J. Blake, Claire Wilson, Polly L. Arnold


View Original

Abstract

The tetravalent organometallic cerium complex [CeL4] is readily accessible from the oxidation of the trivalent [CeL3], L = a bidentate N-heterocyclic carbene alkoxide ligand, [C{(NPri)CHCHN}CH2CMe2O]. The [CeL4] complex should behave like the [UL4] analogue, but the two complexes show significantly different structures, highlighting the differences between 4f and 5f metals.

Related Literature

Inside back cover

Cover

DOI: 10.1039/C2CP90173K

Limits of metastability in amorphous ices: the neutron scattering Debye–Waller factor

Katrin Amann-Winkel, Florian Löw, Philip H. Handle, Burkhard Geil, Franz Fujara, Thomas Loerting

2012-10-22 Paper

DOI: 10.1039/C2CP42797D

(H3N–BH3)4: the ammonia borane tetramer

Doris Guerra, Jorge David, Albeiro Restrepo

2012-08-13 Paper

DOI: 10.1039/C2CP41765K

Molecular structures of M2N22− (M and N = B, Al, and Ga) clusters using the gradient embedded genetic algorithm

Jordi Poater, Eduard Matito, Miquel Solà

2012-08-24 Paper

DOI: 10.1039/C2CP42210G

Molecular behavior of water in TiO2 nano-slits with varying coverages of carbon: a molecular dynamics simulation study

Ming-Jie Wei, Luzheng Zhang, Linghong Lu, Yudan Zhu, Keith E. Gubbins, Xiaohua Lu

2012-05-28 Paper

DOI: 10.1039/C2CP40687J

Catalytic activity of Co–Nx/C electrocatalysts for oxygen reduction reaction: a density functional theory study

Shyam Kattel, Plamen Atanassov, Boris Kiefer

2012-10-19 Paper

DOI: 10.1039/C2CP42609A

Solution-processed vanadium oxide as a hole collection layer on an ITO electrode for high-performance polymer solar cells

Zhan'ao Tan, Wenqing Zhang, Chaohua Cui, Yuqin Ding, Deping Qian, Qi Xu, Liangjie Li, Shusheng Li, Yongfang Li

2012-09-10 Paper

DOI: 10.1039/C2CP43125D

Theoretical and experimental studies of water interaction in acetate based ionic liquids

Krishnan Damodaran, Hunaid B. Nulwala, David R. Luebke

2012-10-08 Paper

DOI: 10.1039/C2CP42975F

Hybrid density functional study of band alignment in ZnO–GaN and ZnO–(Ga1−xZnx)(N1−xOx)–GaN heterostructures

Zhenhai Wang, Mingwen Zhao, Xiaopeng Wang, Yan Xi, Xiujie He, Xiangdong Liu, Shishen Yan

2012-09-25 Paper

DOI: 10.1039/C2CP42115A

Does the real ReN2 have the MoS2 structure?

Yachun Wang, Tiankai Yao, Jin-Lei Yao, Jingwu Zhang, Huiyang Gou

2012-10-23 Paper

DOI: 10.1039/C2CP43010J

You might also like

Compound Q&A

What precautions should be taken when handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3)?

When handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3), safety go...

40716-16-34-Methyl-6-(trifluor...
Compound Q&A

What is 4-(3,5-Difluorophenyl)aniline (CAS: 405058-00-6)?

4-(3,5-Difluorophenyl)aniline is an aromatic organic compound with the CAS numbe...

405058-00-64-(3,5-Difluoropheny...
Compound Q&A

How is 5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid (CAS: 338982-07-3) typically synthesized?

5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid can ...

338982-07-35-{[4-(Trifluorometh...
Compound Q&A

What is the market or research trend for 4-Benzylaniline hydrochloride (CAS: 6317-57-3)?

The market for 4-Benzylaniline hydrochloride (CAS: 6317-57-3) is steadily growin...

6317-57-34-Benzylaniline hydr...
Compound Q&A

Is [3-(Diethylsulfamoyl)phenyl]boronic acid (CAS: 871329-58-7) safe?

[3-(Diethylsulfamoyl)phenyl]boronic acid is generally considered safe when handl...

871329-58-7[3-(Diethylsulfamoyl...
Compound Q&A

What are the main uses of 3-Bromo-2,5-dimethoxyaniline (CAS: 115929-62-9)?

3-Bromo-2,5-dimethoxyaniline is mainly used in the pharmaceutical and chemical i...

115929-62-93-Bromo-2,5-dimethox...
Compound Q&A

What regulatory guidelines apply to N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7)?

N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7) is subject to ...

915922-67-7N-Methyl-1-(5-methyl...
Compound Q&A

What industries use Carbamic acid, N-[(5S)-5,6-diamino-6-oxohexyl]-, 1,1-dimethylethyl ester (CAS: 24828-96-4)?

This compound is primarily used in the pharmaceutical industry for the synthesis...

24828-96-4Carbamic acid, N-[(5...
Compound Q&A

How should 2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) be stored?

2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) sho...

1298101-47-92-Methyl-2-propanyl ...
Compound Q&A

What industries use Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9)?

Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9) is utilized in the pharma...

367-33-9Ethyl 2-bromo-4,4,4-...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.