Ansa-tris(allyl) complexes of alkali metals: tripodal analogues of cyclopentadienyl and ansa-metallocene ligands‡
Literature Information
Publication Date
2007-10-04
DOI
10.1039/B712285C
Impact Factor
6.222
Authors
Richard A. Layfield, Felipe García, Julien Hannauer, Simon M. Humphrey
View Original
Abstract
Alkali metal complexes of two types of ansa-tris(allyl) ligand are reported; a monoanionic ansa-tris(allyl) ligand containing tin(II) is formally valence isoelectronic to the cyclopentadienyl ligand and a trianionic ansa-tris(allyl) ligand containing silicon(IV) is formally valence isoelectronic to an ansa-metallocene ligand; the potential wider use of these tripodal ligands in coordination chemistry is discussed.
Recommended Journals
Proceedings of the National Academy of Sciences of the United States of America
Pharmacological Reviews
Russian Chemical Reviews
European Journal of Wood and Wood Products
Molecular Pharmacology
Kinetics and Catalysis
Fibre Chemistry
Journal of Physics and Chemistry of Solids
Science Progress
Helvetica Chimica Acta
Related Literature
Effect of hydrogen in controlling the structural orientation of ZnO:Ga:H as transparent conducting oxide films suitable for applications in stacked layer devices
Praloy Mondal, Debajyoti Das
2016-06-30
Paper
DOI: 10.1039/C6CP03613A
Computational insights into CdSe quantum dots' interactions with acetate ligands
Patrick K. Tamukong, Wadumesthrige D. N. Peiris, Svetlana Kilina
2016-07-04
Paper
DOI: 10.1039/C6CP01665K
A chemical chaperone induces inhomogeneous conformational changes in flexible proteins
Djemel Hamdane, Christophe Velours, David Cornu, Magali Nicaise, Murielle Lombard, Marc Fontecave
2016-07-01
Paper
DOI: 10.1039/C6CP03635J
Ion segregation in an ionic liquid confined within chitosan based chemical ionogels
A. Guyomard-Lack, N. Buchtová, B. Humbert, J. Le Bideau
2015-08-10
Paper
DOI: 10.1039/C5CP04198H
π-Ring currents in doped coronenes with nitrogen and boron: diatropic–paratropic duality
Inmaculada García Cuesta, Barnaby Pownall, Stefano Pelloni, Alfredo M. Sánchez de Merás
2015-08-26
Paper
DOI: 10.1039/C5CP03732H
Near infrared absorbing near infrared emitting highly-sensitive luminescent nanothermometer based on Nd3+ to Yb3+ energy transfer
Ł. Marciniak, A. Bednarkiewicz, M. Stefanski, R. Tomala, D. Hreniak, W. Strek
2015-08-17
Paper
DOI: 10.1039/C5CP03861H
Aqueous biphasic systems composed of ionic liquids and polypropylene glycol: insights into their liquid–liquid demixing mechanisms
Catarina M. S. S. Neves, Jesus Lemus, Jorge F. B. Pereira, Mara G. Freire, João A. P. Coutinho
2016-06-24
Paper
DOI: 10.1039/C6CP04023C
Separation of thorium ions from wolframite and scandium concentrates using graphene oxide
Ondřej Jankovský, David Sedmidubský, Petr Šimek, Kateřina Klímová, Daniel Bouša, Chris Boothroyd, Zdeněk Sofer
2015-08-27
Paper
DOI: 10.1039/C5CP04384K
Formation of a thermally stable bilayer of coadsorbed intact and deprotonated thymine exploiting the surface corrugation of rutile TiO2(110)
J. H. K. Pfisterer, P. S. Deimel, R. G. Acres, M. Fritton, P. Feulner, J. V. Barth, F. Allegretti
2016-07-05
Paper
DOI: 10.1039/C6CP02541B
Non-covalent interaction of benzene with methanol and diethyl ether solid surfaces
Demian Marchione, Martin R. S. McCoustra
2016-07-07
Paper
DOI: 10.1039/C6CP01787H
You might also like
Compound Q&A
What precautions should be taken when handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3)?
When handling 4-Methyl-6-(trifluoromethyl)quinoline (CAS: 40716-16-3), safety go...
40716-16-34-Methyl-6-(trifluor...
Compound Q&A
What is 4-(3,5-Difluorophenyl)aniline (CAS: 405058-00-6)?
4-(3,5-Difluorophenyl)aniline is an aromatic organic compound with the CAS numbe...
405058-00-64-(3,5-Difluoropheny...
Compound Q&A
How is 5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid (CAS: 338982-07-3) typically synthesized?
5-{[4-(Trifluoromethyl)phenyl]sulfanyl}-1,2,3-thiadiazole-4-carboxylic acid can ...
338982-07-35-{[4-(Trifluorometh...
Compound Q&A
What is the market or research trend for 4-Benzylaniline hydrochloride (CAS: 6317-57-3)?
The market for 4-Benzylaniline hydrochloride (CAS: 6317-57-3) is steadily growin...
6317-57-34-Benzylaniline hydr...
Compound Q&A
Is [3-(Diethylsulfamoyl)phenyl]boronic acid (CAS: 871329-58-7) safe?
[3-(Diethylsulfamoyl)phenyl]boronic acid is generally considered safe when handl...
871329-58-7[3-(Diethylsulfamoyl...
Compound Q&A
What are the main uses of 3-Bromo-2,5-dimethoxyaniline (CAS: 115929-62-9)?
3-Bromo-2,5-dimethoxyaniline is mainly used in the pharmaceutical and chemical i...
115929-62-93-Bromo-2,5-dimethox...
Compound Q&A
What regulatory guidelines apply to N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7)?
N-Methyl-1-(5-methyl-1H-indol-3-yl)methanamine (CAS: 915922-67-7) is subject to ...
915922-67-7N-Methyl-1-(5-methyl...
Compound Q&A
What industries use Carbamic acid, N-[(5S)-5,6-diamino-6-oxohexyl]-, 1,1-dimethylethyl ester (CAS: 24828-96-4)?
This compound is primarily used in the pharmaceutical industry for the synthesis...
24828-96-4Carbamic acid, N-[(5...
Compound Q&A
How should 2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) be stored?
2-Methyl-2-propanyl [(1S,3R)-3-aminocyclohexyl]carbamate (CAS: 1298101-47-9) sho...
1298101-47-92-Methyl-2-propanyl ...
Compound Q&A
What industries use Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9)?
Ethyl 2-bromo-4,4,4-trifluorobutanoate (CAS: 367-33-9) is utilized in the pharma...
367-33-9Ethyl 2-bromo-4,4,4-...
Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry
Recommended Compounds
5,10,15,20-tetrakis(4-boronic acid pinacol ester phenyl) porphyrin
CAS Number:
1332748-00-1
Molecular Formula:
C68H74B4N4O8
![2-[(5Z,8Z,11Z,14Z)-5,8,11,14-Icosatetraen-1-yloxy]-1,3-propanediol structure](https://static.chemtradehub.com/structs/222/222723-55-9-0348.webp "2-[(5Z,8Z,11Z,14Z)-5,8,11,14-Icosatetraen-1-yloxy]-1,3-propanediol structure")
2-[(5Z,8Z,11Z,14Z)-5,8,11,14-Icosatetraen-1-yloxy]-1,3-propanediol
CAS Number:
222723-55-9
Molecular Formula:
C23H40O3
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.