Ansa-tris(allyl) complexes of alkali metals: tripodal analogues of cyclopentadienyl and ansa-metallocene ligands‡
Literature Information
Richard A. Layfield, Felipe García, Julien Hannauer, Simon M. Humphrey
Alkali metal complexes of two types of ansa-tris(allyl) ligand are reported; a monoanionic ansa-tris(allyl) ligand containing tin(II) is formally valence isoelectronic to the cyclopentadienyl ligand and a trianionic ansa-tris(allyl) ligand containing silicon(IV) is formally valence isoelectronic to an ansa-metallocene ligand; the potential wider use of these tripodal ligands in coordination chemistry is discussed.
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