Ansa-tris(allyl) complexes of alkali metals: tripodal analogues of cyclopentadienyl and ansa-metallocene ligands‡

Literature Information

Publication Date 2007-10-04
DOI 10.1039/B712285C
Impact Factor 6.222
Authors

Richard A. Layfield, Felipe García, Julien Hannauer, Simon M. Humphrey


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Abstract

Alkali metal complexes of two types of ansa-tris(allyl) ligand are reported; a monoanionic ansa-tris(allyl) ligand containing tin(II) is formally valence isoelectronic to the cyclopentadienyl ligand and a trianionic ansa-tris(allyl) ligand containing silicon(IV) is formally valence isoelectronic to an ansa-metallocene ligand; the potential wider use of these tripodal ligands in coordination chemistry is discussed.

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