A phase separable polycarbonate polymerization catalyst
Literature Information
Chayanant Hongfa, Jianhua Tian, Jeremy Andreatta, Donald J. Darensbourg, David E. Bergbreiter
Polyisobutylene is shown to be a nonpolar phase tag that separates a highly colored salen Cr(III) complex from products but is otherwise kinetically similar to a low molecular weight salen Cr(III) complex in polycarbonate formation by Cr(III)-catalyzed copolymerization of CO2 and cyclohexene oxide.
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