A discrete conglomerate of a distorted Mo(v)-porphyrin with a directly coordinated keggin-type polyoxometalate
Literature Information
Atsutoshi Yokoyama, Takahiko Kojima, Kei Ohkubo, Shunichi Fukuzumi
The reaction of a saddle-distorted Mo(V)-dodecaphenylporphyrin complex and a Keggin-type polyoxometalate gives a discrete and nanosized molecule, [{Mo(DPP)(O)}2(H2SiW12O40)], which involves direct coordination between the Mo(V) centers and terminal oxo groups of the polyoxometalate and exhibits excellent stability in solution to show reversible multi-redox processes.
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![L-Threonine, N-[[4,7,10-tris(carboxymethyl)-1,4,7,10-tetraazacyclododec-1-yl]acetyl]-D-phenylalanyl-L-cysteinyl-L-tyrosyl-D-tryptophyl-L-lysyl-L-threonyl-L-cysteinyl-, cyclic (2→7)-disulfide, acetate (salt) (9CI) structure L-Threonine, N-[[4,7,10-tris(carboxymethyl)-1,4,7,10-tetraazacyclododec-1-yl]acetyl]-D-phenylalanyl-L-cysteinyl-L-tyrosyl-D-tryptophyl-L-lysyl-L-threonyl-L-cysteinyl-, cyclic (2→7)-disulfide, acetate (salt) (9CI) structure](https://static.chemtradehub.com/structs/177/177943-89-4-6312.webp)

