A discrete conglomerate of a distorted Mo(v)-porphyrin with a directly coordinated keggin-type polyoxometalate

Literature Information

Publication Date 2007-06-08
DOI 10.1039/B704994C
Impact Factor 6.222
Authors

Atsutoshi Yokoyama, Takahiko Kojima, Kei Ohkubo, Shunichi Fukuzumi


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Abstract

The reaction of a saddle-distorted Mo(V)-dodecaphenylporphyrin complex and a Keggin-type polyoxometalate gives a discrete and nanosized molecule, [{Mo(DPP)(O)}2(H2SiW12O40)], which involves direct coordination between the Mo(V) centers and terminal oxo groups of the polyoxometalate and exhibits excellent stability in solution to show reversible multi-redox processes.

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