Hydrogen-bond quenching of photodecarbonylation in the solid state and recovery of reactivity by co-crystallization‡
Literature Information
Jing Zhang, Milan Gembicky, Marc Messerschmidt, Philip Coppens
Intermolecular H-bonding between CO (ketone) and HO (4′-hydroxyphenyl) quenches photodecarbonylation of 2,2,4,4-tetramethyl-1,3-di(4′-hydroxyphenyl)acetone 1 in the crystalline solid state, its reactivity is recovered by co-crystallization with the small organic molecule 4,4′-bicyclohexanone.
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