Hydrogen-bond quenching of photodecarbonylation in the solid state and recovery of reactivity by co-crystallization‡

Literature Information

Publication Date 2007-03-09
DOI 10.1039/B700073A
Impact Factor 6.222
Authors

Jing Zhang, Milan Gembicky, Marc Messerschmidt, Philip Coppens


View Original

Abstract

Intermolecular H-bonding between CO (ketone) and HO (4′-hydroxyphenyl) quenches photodecarbonylation of 2,2,4,4-tetramethyl-1,3-di(4′-hydroxyphenyl)acetone 1 in the crystalline solid state, its reactivity is recovered by co-crystallization with the small organic molecule 4,4′-bicyclohexanone.

Related Literature

SUPRAphos-based palladiumcatalysts for the kinetic resolution of racemic cyclohexenyl acetate

Xiao-Bin Jiang, Piet W. N. M. van Leeuwen, Joost N. H. Reek

2007-03-06 Communication

DOI: 10.1039/B700156H

Umbrella motion in aziridines: use of simple chemical inputs to reversibly control the rate of pyramidal inversion

Mark W. Davies, Adam J. Clarke, Guy J. Clarkson, Michael Shipman, James H. R. Tucker

2007-10-03 Communication

DOI: 10.1039/B712447C

Back matter

Front/Back Matter

DOI: 10.1039/B707362N

Investigating organocatalytic reactions: mass spectrometric studies of a conjugate umpolung reaction

Wolfgang Schrader, Peni Purwa Handayani, Christian Burstein, Frank Glorius

2006-12-07 Communication

DOI: 10.1039/B613862D

Supramolecular synthon polymorphism in 2 : 1 co-crystal of 4-hydroxybenzoic acid and 2,3,5,6-tetramethylpyrazine‡

B. R. Sreekanth, Peddy Vishweshwar, K. Vyas

2007-03-09 Communication

DOI: 10.1039/B700082K

Magnetic exchange coupling tunable by means of selective cation binding into poly(radical-armed) azacrowns

Kazuki Igarashi, Takashi Nogami

2006-10-31 Communication

DOI: 10.1039/B613637K

High-connectivity networks: characterization of the first uninodal 9-connected net and two topologically novel 7-connected nets

J. Jacob Morris, Bruce C. Noll, Kenneth W. Henderson

2007-10-12 Communication

DOI: 10.1039/B711668C

Icosahedral galloxane clusters

Robert M. McKinlay, Scott J. Dalgarno, Peter J. Nichols, Stavroula Papadopoulos, Jerry L. Atwood, Colin L. Raston

2007-03-15 Communication

DOI: 10.1039/B700984D

Maximizing the relaxivity of HSA-bound gadolinium complexes by simultaneous optimization of rotation and water exchange

Stefano Avedano, Lorenzo Tei, Alberto Lombardi, Giovanni B. Giovenzana, Silvio Aime, Dario Longo, Mauro Botta

2007-10-26 Communication

DOI: 10.1039/B714438E

Synthesis of AgBiS2 microspheres by a templating method and their catalytic polymerization of alkylsilanes

Jiaqiang Wang, Xikung Yang, Wenbing Hu, Bin Li, Jiangmei Yan, Jinjin Hu

2007-09-19 Communication

DOI: 10.1039/B710832J

You might also like

Compound Q&A

What regulatory guidelines apply to 4-Amino-3-bromophenol (CAS: 74440-80-5)?

4-Amino-3-bromophenol (CAS: 74440-80-5) falls under the classification of a haza...

74440-80-54-Amino-3-bromopheno...
Compound Q&A

How should (17beta)-3-Oxoestr-4-en-17-yl acetate (CAS: 1425-10-1) be stored?

(17beta)-3-Oxoestr-4-en-17-yl acetate should be stored in a cool, dry place away...

1425-10-1(17beta)-3-Oxoestr-4...
Compound Q&A

What are the physical and chemical properties of 2-[(2,2-Diethoxyethyl)disulfanyl]-1,1-diethoxyethane (CAS: 76505-71-0)?

2-[(2,2-Diethoxyethyl)disulfanyl]-1,1-diethoxyethane (CAS: 76505-71-0) is a colo...

76505-71-02-[(2,2-Diethoxyethy...
Compound Q&A

What is the market or research trend for 1-(β-D-ribofuranosyl)-1H-imidazo[4,5-c]pyridin-4-amine?

The market and research for 1-(β-D-ribofuranosyl)-1H-imidazo[4,5-c]pyridin-4-ami...

6736-58-91-(beta-D-Ribofurano...
Compound Q&A

How should waste containing Conjugated Estrogen (CAS: 12126-59-9) be handled?

Waste containing Conjugated Estrogen (CAS: 12126-59-9) should be collected and d...

12126-59-9Conjugated Estrogen
Compound Q&A

What is the market or research trend for Bis(2,2,2-trifluoroethyl) (methoxycarbonylmethyl)phosphonate?

The market for Bis(2,2,2-trifluoroethyl) (methoxycarbonylmethyl)phosphonate (CAS...

88738-78-7Bis(2,2,2-trifluoroe...
Compound Q&A

Are there alternatives to 3,4'-Di-O-methylellagic acid (CAS: 57499-59-9) in synthesis?

There are several alternatives to 3,4'-Di-O-methylellagic acid (CAS: 57499-59-9)...

57499-59-93,4'-Di-O-methylella...
Compound Q&A

What regulatory guidelines apply to 2-Chloro-N,N-dimethylpyridin-4-amine (CAS: 59047-70-0)?

2-Chloro-N,N-dimethylpyridin-4-amine (CAS: 59047-70-0) is regulated under the Gl...

59047-70-02-Chloro-N,N-dimethy...
Compound Q&A

What is cerium(3+);oxygen(2-);vanadium(5+) (CAS: 13597-19-8)?

Cerium(3+);oxygen(2-);vanadium(5+) (CAS: 13597-19-8) is a complex inorganic comp...

13597-19-8cerium(3+);oxygen(2-...
Compound Q&A

Is 7-Chloro-1-iodoisoquinoline (CAS: 1203579-27-4) safe?

7-Chloro-1-iodoisoquinoline (CAS: 1203579-27-4) is generally considered safe whe...

1203579-27-47-Chloro-1-iodoisoqu...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.