Umbrella motion in aziridines: use of simple chemical inputs to reversibly control the rate of pyramidal inversion

Literature Information

Publication Date 2007-10-03
DOI 10.1039/B712447C
Impact Factor 6.222
Authors

Mark W. Davies, Adam J. Clarke, Guy J. Clarkson, Michael Shipman, James H. R. Tucker


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Abstract

The molecular motion associated with atomic inversion at an aziridine nitrogen can be essentially halted by metal complexation; addition of a second chemical input that decomplexes the metal from the aziridine restores fast inversion (k = 40 s–1 at 303 K).

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