Icosahedral galloxane clusters

Literature Information

Publication Date 2007-03-15
DOI 10.1039/B700984D
Impact Factor 6.222
Authors

Robert M. McKinlay, Scott J. Dalgarno, Peter J. Nichols, Stavroula Papadopoulos, Jerry L. Atwood, Colin L. Raston


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Abstract

Hydrolysis of ‘tris(aryl or alkyl)gallium(III)’ species results in the formation of spheroidal dodecameric galloxane mixed oxide–hydroxide clusters, and shows that the gallium centres and associated residual alkyl/aryl groups are arranged at the polyhedral vertices of pseudo-icosahedra.

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