A new coupling reaction for the synthesis of ruthenium half-sandwich complexes with sterically demanding cyclopentadienyl ligands

Literature Information

Publication Date 2007-02-09
DOI 10.1039/B618712A
Impact Factor 6.222
Authors

Sébastien Gauthier, Euro Solari, Barnali Dutta, Rosario Scopelliti, Kay Severin


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Abstract

The reaction of RuCl3(solv.)n with tert-butylacetylene in methanol or ethanol leads to the formation of chloro-bridged half-sandwich complexes with sterically demanding cyclopentadienyl ligands, which are of high interest as starting materials for the synthesis of novel Ru catalysts.

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Back matter

Front/Back Matter

DOI: 10.1039/B906548M

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