A new coupling reaction for the synthesis of ruthenium half-sandwich complexes with sterically demanding cyclopentadienyl ligands
Literature Information
Sébastien Gauthier, Euro Solari, Barnali Dutta, Rosario Scopelliti, Kay Severin
The reaction of RuCl3(solv.)n with tert-butylacetylene in methanol or ethanol leads to the formation of chloro-bridged half-sandwich complexes with sterically demanding cyclopentadienyl ligands, which are of high interest as starting materials for the synthesis of novel Ru catalysts.
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