Copper sulfide nanostripe patterns at the Au(111)/electrolyte interface studied by in situSTM

Literature Information

Publication Date 2007-02-22
DOI 10.1039/B616586A
Impact Factor 3.676
Authors

Daniel Friebel, Christian Schlaup, Peter Broekmann, Klaus Wandelt


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Abstract

One monolayer of Cu was prepared on Au(111) by underpotential deposition from CuSO4/H2SO4 solution and, by two electrolyte exchanges for (i) Cu-free H2SO4 and (ii) NaOH/Na2S solution, exposed to bisulfide. This procedure leads to several incommensurate phases with characteristic stripe patterns. These are irreversibly displaced upon cathodic potential sweeps by different structures, which, after returning to the initial potential, transform into the rectangular CuxS phase already known for the sulfidation of a Cu submonolayer on Au(111).

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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