Single-crystal to single-crystal phase transitions of bis(N-phenylisonicotinamide)silver(i) nitrate reveal cooperativity properties in porous molecular materials

Literature Information

Publication Date 2007-01-30
DOI 10.1039/B616502H
Impact Factor 6.222
Authors

Partha S. Mukherjee, Nazario Lopez, Atta M. Arif, Francisco Cervantes-Lee, Juan C. Noveron


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Abstract

Two single-crystal to single-crystal phase transitions in trans-[Ag(NPI)2](NO3)·2CH3OH (1a), (NPI = N-phenylisonicotinamide) were characterized with X-ray crystallography; the first transition is reversible and arises from a desolvation transition induced by vacuum and generated 1b; the second transition was induced by heat at 140 °C and generated 1c.

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