Supported ionic liquid phase catalysis with supercritical flow

Literature Information

Publication Date 2007-01-31
DOI 10.1039/B616186C
Impact Factor 6.222
Authors

Ulrich Hintermair, Guoying Zhao, Catherine C. Santini, Mark J. Muldoon, David J. Cole-Hamilton


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Abstract

Rapid hydroformylation of 1-octene (rates up to 800 h−1) with the catalyst remaining stable for at least 40 h and with very low rhodium leaching levels (0.5 ppm) is demonstrated when using a system involving flowing the substrate, reacting gases and products dissolved in supercritical CO2 (scCO2) over a fixed bed supported ionic liquid phase catalyst.

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