Supported ionic liquid phase catalysis with supercritical flow
Literature Information
Ulrich Hintermair, Guoying Zhao, Catherine C. Santini, Mark J. Muldoon, David J. Cole-Hamilton
Rapid hydroformylation of 1-octene (rates up to 800 h−1) with the catalyst remaining stable for at least 40 h and with very low rhodium leaching levels (0.5 ppm) is demonstrated when using a system involving flowing the substrate, reacting gases and products dissolved in supercritical CO2 (scCO2) over a fixed bed supported ionic liquid phase catalyst.
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![N-[4-(Cyanoethynyl)phenyl]-16-oxo-4,7,10,13-tetraoxa-17-azahenicos-1-yn-21-amide structure N-[4-(Cyanoethynyl)phenyl]-16-oxo-4,7,10,13-tetraoxa-17-azahenicos-1-yn-21-amide structure](https://static.chemtradehub.com/structs/218/2183440-36-8-68cb.webp)



