Promoting helicity in carbohydrate-containing foldamers through long-range hydrogen bonds
Literature Information
David Rodríguez-Lucena, Juan M. Benito, Carmen Ortiz Mellet, José M. García Fernández
A sensor system to probe the propensity of carbohydrates to induce helical structures through long-range hydrogen bonds, based on a C2-symmetric xylylene bis(thiourea) arrangement, is reported; the formation of intermolecular complexes with benzoate anion promotes helix uncoiling, the free energy of the process being related to helix stability.
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![7-Bromo-5-chloro-1H-pyrazolo[4,3-b]pyridine structure 7-Bromo-5-chloro-1H-pyrazolo[4,3-b]pyridine structure](https://static.chemtradehub.com/structs/135/1351813-70-1-a716.webp)

