Promoting helicity in carbohydrate-containing foldamers through long-range hydrogen bonds
Literature Information
Publication Date
2006-11-27
DOI
10.1039/B614294J
Impact Factor
6.222
Authors
David Rodríguez-Lucena, Juan M. Benito, Carmen Ortiz Mellet, José M. García Fernández
View Original
Abstract
A sensor system to probe the propensity of carbohydrates to induce helical structures through long-range hydrogen bonds, based on a C2-symmetric xylylene bis(thiourea) arrangement, is reported; the formation of intermolecular complexes with benzoate anion promotes helix uncoiling, the free energy of the process being related to helix stability.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry
Recommended Compounds
amine structure](https://static.chemtradehub.com/structs/629/62924-61-2-0728.webp "[(2-chlorophenyl)methyl](ethyl)amine structure")
(2R,2'R)-1,1'-Bis(2-pyridinylmethyl)-2,2'-bipyrrolidine tetrahydrochloride
CAS Number:
1228077-88-0
Molecular Formula:
C20H30Cl4N4
5-Bromo-2-chloro-N-methoxy-N-methylisonicotinamide
CAS Number:
1256790-08-5
Molecular Formula:
C8H8BrClN2O2
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