Promoting helicity in carbohydrate-containing foldamers through long-range hydrogen bonds
Literature Information
David Rodríguez-Lucena, Juan M. Benito, Carmen Ortiz Mellet, José M. García Fernández
A sensor system to probe the propensity of carbohydrates to induce helical structures through long-range hydrogen bonds, based on a C2-symmetric xylylene bis(thiourea) arrangement, is reported; the formation of intermolecular complexes with benzoate anion promotes helix uncoiling, the free energy of the process being related to helix stability.
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amine structure [(2-chlorophenyl)methyl](ethyl)amine structure](https://static.chemtradehub.com/structs/629/62924-61-2-0728.webp)


