A tetradecanuclear copper dimeric macrocyclic complex with a body-centred heptanuclear core-structure and magnetism

Literature Information

Publication Date 2006-11-23
DOI 10.1039/B612795A
Impact Factor 6.222
Authors

Santokh S. Tandon, Scott D. Bunge, Laurence K. Thompson


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Abstract

2,6-Diformyl-4-methylphenol and 1,3-diamino-2-hydroxypropane template condense in the presence of Cu(NO3)2 and azide to produce a 3 : 3 macrocyclic ring containing an unprecedented grouping of seven copper(II) ions within the macrocyclic cavity, with the seventh metal completing a body-centred heptanuclear lattice.

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