Lewis base stabilized lithium TMP-aluminates: an unexpected fragmentation and capture reaction involving cyclic ether 1,4-dioxane
Literature Information
Joaquín García-Álvarez, Eva Hevia, Alan R. Kennedy, Jan Klett, Robert E. Mulvey
Three Lewis base variations of the synthetically useful aluminate [L·Li(TMP)(iBu)Al(iBu)2], where L is TMPH, Et3N or PhC(O)NiPr2, are reported, together with the reaction of the benzamide complex with 1,4-dioxane, which surprisingly leads to fragmentation of the cyclic ether and capture of its alkoxy vinyl ether residue within a novel dilithium dialuminium hexaalkyl aggregate.
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