Enantioselective nitroaldol (Henry) reaction using copper(ii) complexes of (−)-sparteine
Literature Information
H. Maheswaran, K. Leon Prasanth, G. Gopi Krishna, K. Ravikumar, B. Sridhar, M. Lakshmi Kantam
The dichloro[(−)-sparteine-N,N′]copper(II) complex provides Henry adducts with high enantioselectivities (73–97% ee) in Henry reaction between nitromethane and various aldehydes.
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![4-chloro-N-[5-methyl-2-(7H-pyrrolo[2,3-d]pyrimidine-4-carbonyl)-3-pyridyl]-3-(trifluoromethyl)benzenesulfonamide structure 4-chloro-N-[5-methyl-2-(7H-pyrrolo[2,3-d]pyrimidine-4-carbonyl)-3-pyridyl]-3-(trifluoromethyl)benzenesulfonamide structure](https://static.chemtradehub.com/structs/110/1100318-47-5-127d.webp)



