![4-(4-{4-[4-Fluoro-3-(trifluoromethyl)phenyl]-1-methyl-1H-imidazol-2-yl}-1-piperidinyl)-1H-pyrazolo[3,4-d]pyrimidine 4-methylbenzenesulfonate (1:1) structure](https://static.chemtradehub.com/structs/108/1082949-68-5-00b6.webp "4-(4-{4-[4-Fluoro-3-(trifluoromethyl)phenyl]-1-methyl-1H-imidazol-2-yl}-1-piperidinyl)-1H-pyrazolo[3,4-d]pyrimidine 4-methylbenzenesulfonate (1:1) structure")
4-(4-{4-[4-Fluoro-3-(trifluoromethyl)phenyl]-1-methyl-1H-imidazol-2-yl}-1-piperidinyl)-1H-pyrazolo[3,4-d]pyrimidine 4-methylbenzenesulfonate (1:1)
CAS Number:
1082949-68-5
Molecular Formula:
C28H27F4N7O3S
Enantioselective nitroaldol (Henry) reaction using copper(ii) complexes of (−)-sparteine
Literature Information
Publication Date
2006-09-14
DOI
10.1039/B610203D
Impact Factor
6.222
Authors
H. Maheswaran, K. Leon Prasanth, G. Gopi Krishna, K. Ravikumar, B. Sridhar, M. Lakshmi Kantam
View Original
Abstract
The dichloro[(−)-sparteine-N,N′]copper(II) complex provides Henry adducts with high enantioselectivities (73–97% ee) in Henry reaction between nitromethane and various aldehydes.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry
Recommended Compounds
methanone structure](https://static.chemtradehub.com/structs/814/81449-01-6-786d.webp "[4-(Hydroxymethyl)phenyl](phenyl)methanone structure")
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