Highly-oxidised, sulfur-rich, mixed-valence vanadium(iv/v) complexes

Literature Information

Publication Date 2006-09-05
DOI 10.1039/B610036H
Impact Factor 6.222
Authors

Michelle K. Taylor, David J. Evans, Charles G. Young


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Abstract

The reactions of [V2(μ-S2)2(S2CNR2)4] (R = alkyl) with NOBF4 produce highly-oxidised, sulfur-rich, V(IV/V) complexes, [V2(μ-S2)2(S2CNR2)4]BF4, that exhibit 15-line EPR spectra and structures consistent with Class III mixed-valence behaviour.

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