Highly-oxidised, sulfur-rich, mixed-valence vanadium(iv/v) complexes
Literature Information
Michelle K. Taylor, David J. Evans, Charles G. Young
The reactions of [V2(μ-S2)2(S2CNR2)4] (R = alkyl) with NOBF4 produce highly-oxidised, sulfur-rich, V(IV/V) complexes, [V2(μ-S2)2(S2CNR2)4]BF4, that exhibit 15-line EPR spectra and structures consistent with Class III mixed-valence behaviour.
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