Controlled diastereoselectivity at the alkene-geometry through selective encapsulation: E-Zphotoisomerization of oxazolidinone-functionalized enecarbamates within hydrophobic nano-cavities
Literature Information
J. Sivaguru, Steffen Jockusch, Joanne Dyer, Waldemar Adam
Photoisomerization of encapsulated Z-enecarbamates within the hydrophobic chiral cavities of γ-CD showed higher diastereoselectivities in the photoproducts than those obtained in solution. The selective encapsulation of the enecarbamates and the following isomerization process are both diastereoselectively controlled by γ-CD.
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amine structure [(2-chlorophenyl)methyl](ethyl)amine structure](https://static.chemtradehub.com/structs/629/62924-61-2-0728.webp)

![Ethanone, 1-[4-chloro-2-(methylthio)-5-pyrimidinyl]- structure Ethanone, 1-[4-chloro-2-(methylthio)-5-pyrimidinyl]- structure](https://static.chemtradehub.com/structs/661/66116-82-3-863e.webp)

