Parity conservation and polarization of differential cross sections in complex-forming chemical reactions

Literature Information

Publication Date 2006-07-27
DOI 10.1039/B608811B
Impact Factor 3.676
Authors

L. Bonnet, P. Larrégaray, J.-C. Rayez, T. Gonzalez-Lezana


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Abstract

For complex-forming chemical reactions, such as atom–diatom insertion reactions, quantum scattering and quantum statistical calculations usually predict sharp forward/backward peaks in the Differential Cross Sections (DCS). Conversely, the corresponding classical calculations are unable to reproduce these peaks. We show here that the basic reason for such an intriguing failure is that parity conservation is ignored in classical mechanics. A by-product of the analysis is a simple parity-restoring approximation that might significantly increase the ability of classical mechanics to describe DCSs over the whole angular range for the title processes.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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