Coordination polymers undergoing spin crossover and reversible ligand exchange in the solid

Literature Information

Publication Date 2006-09-06
DOI 10.1039/B606434E
Impact Factor 6.222
Authors

Ana Galet, M. Carmen Muñoz, José Antonio Real


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Abstract

Here we report the synthesis and characterisation of a polymer made up of a system of parallel 2-D grids of Fe(II) ions linked by [Au(CN)2]− bridges and its transformation into a new system of three interpenetrated 3-D coordination open frameworks with the NbO topology. Reversibility of this crystal-to-crystal transformation is evidenced by X-ray crystallographic data and from their spin crossover properties.

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