Kinetic studies of reactions of the nitrate radical (NO3) with peroxy radicals (RO2): an indirect source of OH at night?

Literature Information

Publication Date 2006-07-12
DOI 10.1039/B605569A
Impact Factor 3.676
Authors

Dudley E. Shallcross, Laura Watson


View Original

Abstract

A discharge–flow system, coupled to cavity-enhanced absorption spectroscopy (CEAS) detection systems for NO3 at λ = 662 nm and NO2 at λ = 404 nm, was used to investigate the kinetics of the reactions of NO3 with eight peroxy radicals at P ∼ 5 Torr and T ∼ 295 K. Values of the rate constants obtained were (k/10−12 cm3 molecule−1 s−1): CH3O2 (1.1 ± 0.5), C2H5O2 (2.3 ± 0.7), CH2FO2 (1.4 ± 0.9), CH2ClO2 (3.8+1.4−2.6), c-C5H9O2 (1.2+1.1−0.5), c-C6H11O2 (1.9 ± 0.7), CF3O2 (0.62 ± 0.17) and CF3CFO2CF3 (0.24 ± 0.13). We explore possible relationships between k and the orbital energies of the reactants. We also provide a brief discussion of the potential impact of the reactions of NO3 with RO2 on the chemistry of the night-time atmosphere.

Related Literature

Synthesis of β-lactams via diastereoselective, intramolecular Kinugasa reactions

Oskar Popik, Barbara Grzeszczyk, Olga Staszewska-Krajewska, Bartłomiej Furman, Marek Chmielewski

2020-03-16 Paper

DOI: 10.1039/D0OB00228C

The endo-aza-Michael addition in the synthesis of piperidines and pyrrolidines

Roderick W. Bates, Weiting Ko, Viktor Barát

2020-01-16 Review Article

DOI: 10.1039/C9OB02388G

Blue emissive dimethylmethylene-bridged triphenylamine derivatives appending cross-linkable groups

Kangyu Zhou, Hongfei Pan, Yongjie Zhang, Houchen Wang, Xiaofei Dong, Xiangkui Ren, Xianggao Li, Shirong Wang, Zhijian Chen

2020-04-24 Paper

DOI: 10.1039/D0OB00622J

Synthetic approaches towards avibactam and other diazabicyclooctane β-lactamase inhibitors

Laure Peilleron, Kevin Cariou

2020-01-13 Review Article

DOI: 10.1039/C9OB02605C

Toward the total synthesis of grayanane diterpene mollanol A by a Prins [3 + 2] strategy

Jianzhuang Miao, Yi-Xuan Zheng, Shi-Chao Lu, Shi-Peng Zhang, Ya-Ling Gong, Shu Xu

2020-02-15 Communication

DOI: 10.1039/D0OB00160K

A base-promoted tandem approach to bicyclic 8-membered ring ketones

Emerson E. F. dos Santos, Gabriela F. P. de Souza, Deborah A. Simoni, Airton G. Salles, Jr

2020-04-13 Communication

DOI: 10.1039/D0OB00618A

Copper-catalyzed direct amination of benzylic hydrocarbons and inactive aliphatic alkanes with arylamines

Hua Yao, Bo Xie, Xiaoyang Zhong, Shengzhou Jin, Sen Lin, Zhaohua Yan

2020-04-10 Communication

DOI: 10.1039/D0OB00491J

Exploring the relationship between structure and activity in BODIPYs designed for antimicrobial phototherapy

Burkhard Gitter, Keith J. Flanagan, Christopher J. Kingsbury, Mathias O. Senge

2020-03-06 Paper

DOI: 10.1039/D0OB00188K

Rh-Catalyzed C–H activation/intramolecular condensation for the construction of benzo[f]pyrazolo[1,5-a][1,3]diazepines

Yi Ning, Xinwei He, Youpeng Zuo, Jian Wang, Qiang Tang, Mengqing Xie, Ruxue Li, Yongjia Shang

2020-03-20 Paper

DOI: 10.1039/D0OB00382D

You might also like

Compound Q&A

What regulatory guidelines apply to 6-Bromo-2-methylimidazo[1,2-a]pyrimidine (CAS: 1111638-05-1)?

6-Bromo-2-methylimidazo[1,2-a]pyrimidine (CAS: 1111638-05-1) falls under various...

1111638-05-16-Bromo-2-methylimid...
Compound Q&A

Are there alternatives to 1-Pyrrolidineethanol, β-methyl-α-phenyl-, (αS,βR) (CAS: 123620-80-4) in synthesis?

While there are no direct alternatives, similar compounds like 1-Pyrrolidineetha...

123620-80-41-Pyrrolidineethanol...
Compound Q&A

Is 4-Methyl-2,6-bis(2-methyl-2-propanyl)phenyl methylcarbamate (CAS: 1918-11-2) safe?

4-Methyl-2,6-bis(2-methyl-2-propanyl)phenyl methylcarbamate (CAS: 1918-11-2) is ...

1918-11-24-Methyl-2,6-bis(2-m...
Compound Q&A

How should 2-(3-Bromo-4-fluorophenyl)-1,3-dioxolane (CAS: 77771-04-1) be stored?

2-(3-Bromo-4-fluorophenyl)-1,3-dioxolane (CAS: 77771-04-1) should be stored in a...

77771-04-12-(3-Bromo-4-fluorop...
Compound Q&A

What are the physical and chemical properties of 4,5,6,7-Tetrahydro-1H-indazole hydrochloride (CAS: 18161-11-0)?

4,5,6,7-Tetrahydro-1H-indazole hydrochloride is a white crystalline solid with a...

18161-11-04,5,6,7-Tetrahydro-1...
Compound Q&A

What is (2R)-1-Methoxy-3-phenyl-2-propanamine (CAS: 59919-07-2)?

(2R)-1-Methoxy-3-phenyl-2-propanamine is a chiral organic compound with the CAS ...

59919-07-2(2R)-1-Methoxy-3-phe...
Compound Q&A

What industries use Ethyl 1-(1-phenylethyl)-1H-imidazole-5-carboxylate (CAS: 56649-47-9)?

Ethyl 1-(1-phenylethyl)-1H-imidazole-5-carboxylate is used in various industries...

56649-47-9Ethyl 1-(1-phenyleth...
Compound Q&A

What regulatory guidelines apply to 4-[(1E,3S)-1-(4-Hydroxyphenyl)-1,4-pentadien-3-yl]phenol (CAS: 17676-24-3)?

4-[(1E,3S)-1-(4-Hydroxyphenyl)-1,4-pentadien-3-yl]phenol (CAS: 17676-24-3) falls...

17676-24-34-[(1E,3S)-1-(4-Hydr...
Compound Q&A

What industries use (S)-3-Amino-5-phenylpentanoic acid hydrochloride (CAS: 331846-97-0)?

(S)-3-Amino-5-phenylpentanoic acid hydrochloride is primarily used in the pharma...

331846-97-0(S)-3-Amino-5-phenyl...
Compound Q&A

How is 7-methoxy-1-benzothiophene-2-carboxylic acid (CAS: 88791-07-5) typically synthesized?

7-Methoxy-1-benzothiophene-2-carboxylic acid is typically synthesized by reactin...

88791-07-57-methoxy-1-benzothi...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.