An azido–metal–isonicotinate complex showing long-range ordered ferromagnetic interaction: synthesis, structure and magnetic properties

Literature Information

Publication Date 2006-04-24
DOI 10.1039/B601311B
Impact Factor 6.222
Authors

Yong-Fei Zeng, Fu-Chen Liu, Jiong-Peng Zhao, Shuang Cai, Xian-He Bu, Joan Ribas


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Abstract

A new 3D CuII complex [Cu1.5(N3)2(isonicotinate)]n [1], which features two types of bridging modes for azide (μ1,1 and the rare asymmetric μ1,1,3) where the three bonds of the μ1,1,3-N3− group to Cu exhibit three different distances, has been synthesized and characterized, and magnetic measurements indicate that [1] experiences long-range ferromagnetic ordering at approximately 6 K.

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