Balancing framework densification with charged, halogen-bonded-π-conjugated linkages: [PPh4]2{[E-TTF–I2][Re6Se8(CN)6]} versus [PPh4]2[EDT-TTF–I]2{[EDT-TTF–I][Re6Se8(CN)6]}
Literature Information
Anupama Ranganathan, Abdelkrim El-Ghayoury, Cécile Mézière, Etienne Harté, Rodolphe Clérac, Patrick Batail
The ionic character of a set of two redox linkages and strong, directional halogen bonding at the organic–inorganic interface compromise to produce two materials sharing a common two-dimensional net, eventually extended in a third dimension, although two of the six symmetrical halogen bond acceptors ultimately remain uninvolved as a result of charge densification.
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