Samarium diiodide-induced intramolecular pinacol coupling of dinitrones: synthesis of cyclic cis-vicinal diamines

Literature Information

Publication Date 2005-09-30
DOI 10.1039/B511491H
Impact Factor 6.222
Authors

Jean-Philippe Ebran, Rita G. Hazell, Troels Skrydstrup


View Original

Abstract

Pinacol coupling of alkyl dinitrones mediated by SmI2 was achieved in the presence of a proton source allowing the synthesis of cyclic vicinal diamines with good cis-selectivity.

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