![(1S)-1,5-Anhydro-1-[3-(1-benzothiophen-2-ylmethyl)-4-fluorophenyl]-D-glucitol structure](https://static.chemtradehub.com/structs/761/761423-87-4-dbeb.webp "(1S)-1,5-Anhydro-1-[3-(1-benzothiophen-2-ylmethyl)-4-fluorophenyl]-D-glucitol structure")
(1S)-1,5-Anhydro-1-[3-(1-benzothiophen-2-ylmethyl)-4-fluorophenyl]-D-glucitol
CAS Number:
761423-87-4
Molecular Formula:
C21H21FO5S
A CoII complex for 19F MRI-based detection of reactive oxygen species
Literature Information
Publication Date
2016-11-08
DOI
10.1039/C6CC08207F
Impact Factor
6.222
Authors
Meng Yu, Da Xie, Khanh P. Phan, José S. Enriquez, Emily L. Que
View Original
Abstract
A fluorinated, air-stable cobalt(II) complex serves as a turn-on 19F magnetic resonance imaging (MRI) tracer for reactive oxygen species including H2O2. Upon oxidation with H2O2, the complex converts from paramagnetic high spin CoII to diamagnetic low spin CoIII resulting in a chemical shift change and enhancement in 19F NMR signal. Further, the oxidation can be reversed in the presence of reductant Na2S2O4. The turn-on response is demonstrated by 19F MRI, characterized by a ∼2–3 fold enhancement in signal.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
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