A unique example of a 36 tessellated 2-D net based on a tri-nuclear zinc(ii)-1,4-benzenedicarboxylate framework

Literature Information

Publication Date 2005-10-03
DOI 10.1039/B509929C
Impact Factor 6.222
Authors

Colleen A. Williams, Alexander J. Blake, Peter Hubberstey, Martin Schröder


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Abstract

Reaction of Zn(NO3)2 and 1,4-benzenedicarboxylic acid (1,4-H2BDC) at 100 °C for 24 hours in a pressure tube yielded on cooling {[Zn3(1,4-BDC)3(DEF)2]·DEF}∞ (DEF = diethylformamide) incorporating planar six-connected centres to give a unique 36 tessellated 2-D framework polymer.

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