Kinetics of alkanethiol monolayer desorption from gold in air
Literature Information
Mohammad Reza Shadnam, A. Amirfazli
Thermal desorption of an alkanethiol monolayer from a gold substrate into a gaseous medium under ambient pressure was investigated using XPS and it was found that there exist 2 consecutive 1st order kinetics mechanisms with activation energies of 29.9 and 32.7 kcal mol−1, respectively, i.e. on average ∼15% higher than reports for liquid media desorption.
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