Infrared spectrum and structure of the gold dihydroxide molecule

Literature Information

Publication Date 2005-07-12
DOI 10.1039/B506970J
Impact Factor 6.222
Authors

Xuefeng Wang, Lester Andrews


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Abstract

Reactions of laser-ablated gold atoms with H2O2 and H2 + O2 mixtures give four new infrared absorptions, which match the four most intense vibrational frequencies calculated for Au(OH)2 using density functional theory; the calculations find a C2h structure and substantial covalent bonding character for the Au(OH)2 molecule, which is probably due to the high electron affinity of gold.

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