(S)-(9H-Fluoren-9-yl)methyl (pyrrolidin-2-ylmethyl)carbamate hydrochloride
CAS Number:
1217813-15-4
Molecular Formula:
C20H23ClN2O2
Synthesis of silafluorenes and silaindenes via silyl radicals from arylhydrosilanes: intramolecular cyclization and intermolecular annulation with alkynes
Literature Information
Publication Date
2015-03-02
DOI
10.1039/C5QO00012B
Impact Factor
5.281
Authors
Liang Xu, Pengfei Li
View Original
Abstract
Intramolecular homolytic aromatic silylation of biphenyl-2-hydrosilanes via silyl radicals has been developed for the synthesis of silafluorenes. Moreover, silaindenes are synthesized via a silyl radical cascade process, assembling internal alkynes with readily available arylhydrosilanes by C–H and Si–H cleavage and C–C and C–Si bond formation in one step. These represent a new simple and efficient approach towards the synthesis of benzosilole derivatives.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
(2S)-2-(Fluoromethyl)piperidine hydrochloride (1:1)
CAS Number:
886216-73-5
Molecular Formula:
C6H13ClFN
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