Boron-doped diamond microdisc arrays: electrochemical characterisation and their use as a substrate for the production of microelectrode arrays of diverse metals (Ag, Au, Cu) via electrodeposition

Literature Information

Publication Date 2005-08-01
DOI 10.1039/B506956D
Impact Factor 4.616
Authors

Andrew O. Simm, Craig E. Banks, Sarah Ward-Jones, Trevor J. Davies, Nathan S. Lawrence, Timothy G. J. Jones, Li Jiang, Richard G. Compton


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Abstract

A novel boron-doped diamond (BDD) microelectrode array is characterised with electrochemical and atomic force microscopic techniques. The array consists of 40 micron-diameter sized BDD discs which are separated by 250 microns from their nearest neighbour in a hexagonal arrangement. The conducting discs can be electroplated to produce arrays of copper, silver or gold for analytical purposes in addition to operating as an array of BDD-microelectrodes. Proof-of-concept is shown for four separate examples; a gold plated array for arsenic detection, a copper plated array for nitrate analysis, a silver plated array for hydrogen peroxide monitoring and last, cathodic stripping voltammetry for lead at the bare BDD-array.

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