Interfacial defects induced electronic property transformation at perovskite SrVO3/SrTiO3 and LaCrO3/SrTiO3 heterointerfaces

Literature Information

Publication Date 2017-02-01
DOI 10.1039/C6CP07691B
Impact Factor 3.676
Authors

Junjie Li, Deqiang Yin, Qiang Li, Rong Sun, Sumei Huang, Fanzhi Meng


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Abstract

Unravelling the atomic structure and chemical species of interfacial defects is critical to understanding the origin of interfacial properties in many heterojunctions. Here, by combining advanced transmission electron microscopy, spectroscopy and first-principles calculations, we demonstrate interfacial Ti diffusion in SrVO3/SrTiO3 and LaCrO3/SrTiO3 heterointerfaces and uncover that the interfacial defects induce a significant change in electronic properties by showing an electronic transformation from the insulating state to metallic state at SrVO3/SrTiO3 heterointerfaces due to the hybridization of interfacial Ti d, O p and V d, and a metallic to insulating state transformation at LaCrO3/SrTiO3 because of Ti–Cr mixing induced charge redistribution in the interfacial layer.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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