Porous inorganic capsules in action: modelling transmembrane cation-transport parameter-dependence based on water as vehicle‡

Literature Information

Publication Date 2005-07-07
DOI 10.1039/B506087G
Impact Factor 6.222
Authors

Erhard T. K. Haupt, Claudia Wontorra, Dieter Rehder, Achim Müller


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Abstract

Insight into basic principles of cation transport through “molecular channels”, and especially details of the related fundamental H2O vehicle function, could be obtained via7Li NMR studies of the Li+ uptake/release processes by the unique porous nanocapsule [{(MoVI)MoVI5O21(H2O)6}12 {MoV2O4(SO4)}30]72− which behaves as a semi-permeable inorganic membrane open for H2O and small cations; channel traffic as well as internal cavity distribution processes show a strong dependence on “environmental” effects such as exerted by solvent properties, the amount of water present, and competing complexing ligands, and end up in a complex equilibrium situation as in biological leak channels.

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