A new intermediate intercalate in superconducting sodium-doped hafnium nitride chloride
Literature Information
Judith Oró-Solé, Carlos Frontera, Benjamín Martínez, Daniel Beltrán-Porter, Maria Rosa Palacín, Amparo Fuertes
A new phase has been observed during the sodium intercalation of hafnium nitride chloride as intermediate between the host β-HfNCl and the already reported Na0.29HfNCl with Tc of 24 K; the new intermediate shows interlayer spacings ranging from 9.48 to 9.67 Å, corresponds to a second stage intercalate of HfNCl and is superconducting with a critical temperature of 20 K.
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