New routes to manganese higher-nuclearity topologies: synthesis of the cluster [Mn8(μ4-O)4(phpz)8(thf)4]

Literature Information

Publication Date 2005-05-18
DOI 10.1039/B504215A
Impact Factor 6.222
Authors

Stefania Tanase, Guillem Aromí, Elisabeth Bouwman, Huub Kooijman, Anthony L. Spek, Jan Reedijk


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Abstract

Reaction of Mn(ClO4)2·6H2O with 3(5)-methyl-5(3)-(2-hydroxyphenyl)pyrazole (H2phpz) affords a highly asymmetric octanuclear manganese(III) cluster resulting from the different bridging coordination modes of the ligand H2phpz.

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