Harvest of Cu NP anchored magnetic carbon materials from Fe/Cu preloaded biomass: their pyrolysis, characterization, and catalytic activity on aqueous reduction of 4-nitrophenol
Literature Information
Wu-Jun Liu, Ke Tian, Hong Jiang, Han-Qing Yu
In the present study, a value-added Cu NP anchored magnetic carbon (Cu&Fe3O4-mC) material was obtained directly by fast pyrolysis of heavy metal polluted biomass (derived from a biosorption process using fir sawdust to remove Cu(II) from synthetic wastewater). The composition and structure of the Cu&Fe3O4-mC were characterized by various physicochemical techniques, which indicated that the Cu NPs were monodispersed on the mesoporous carbon support with an average particle size of 21.2 nm. The material shows favorable activity and separability on the catalytic reduction of 4-nitrophenol, and can be reused several times without a decrease in the catalytic activity. The maximum release concentration of Cu during the recycling process is 0.7 mg L−1, which is below the limit of the Cu concentration in the surface water. This study would provide a green and sustainable pathway for simultaneous disposal of the biomass waste, removal of the heavy metal pollution, and pretreatment of 4-nitrophenol.
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Green Chemistry provides a unique forum for the publication of innovative research on the development of alternative green and sustainable technologies. The scope of Green Chemistry is based on, but not limited to, the definition proposed by Anastas and Warner (Green Chemistry: Theory and Practice, P T Anastas and J C Warner, Oxford University Press, Oxford, 1998). Green chemistry is the utilisation of a set of principles that reduces or eliminates the use or generation of hazardous substances in the design, manufacture and application of chemical products. Green Chemistry is at the frontiers of this continuously-evolving interdisciplinary science and publishes research that attempts to reduce the environmental impact of the chemical enterprise by developing a technology base that is inherently non-toxic to living things and the environment. Submissions on all aspects of research relating to the endeavour are welcome. The journal publishes original and significant cutting-edge research that is likely to be of wide general appeal. To be published, work must present a significant advance in green chemistry. Papers must contain a comparison with existing methods and demonstrate advantages over those methods before publication can be considered. For more information please see this Editorial. Coverage includes the following, but is not limited to: Design (e.g. biomimicry, design for degradation/recycling/reduced toxicity…) Reagents & Feedstocks (e.g. renewables, CO2, solvents, auxiliary agents, waste utilization…) Synthesis (e.g. organic, inorganic, synthetic biology…) Catalysis (e.g. homogeneous, heterogeneous, enzyme, whole cell…) Process (e.g. process design, intensification, separations, recycling, efficiency…) Energy (e.g. renewable energy, fuels, photovoltaics, fuel cells, energy storage, energy carriers…) Applications (e.g. electronics, dyes, consumer products, coatings, pharmaceuticals, preservatives, building materials, chemicals for industry/agriculture/mining…) Impact (e.g. safety, metrics, LCA, sustainability, (eco)toxicology…) Green chemistry is, by definition, a continuously-evolving frontier. Therefore, the inclusion of a particular material or technology does not, of itself, guarantee that a paper is suitable for the journal. To be suitable, the novel advance should have the potential for reduced environmental impact relative to the state of the art. Green Chemistry does not normally deal with research associated with 'end-of-pipe' or remediation issues.










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