Hybrid catalysts: the synthesis, structure and ethene polymerisation activity of (salicylaldiminato)(pyrrolylaldiminato) titanium complexes
Literature Information
Dale A. Pennington, Simon J. Coles, Michael B. Hursthouse, Manfred Bochmann, Simon J. Lancaster
The mono(salicylaldiminato) complexes Ti{3-tBu-2-(O)C6H3CHN(R)}Cl3(THF) (where R = C6H5, C6F5) react with the metallated pyrrolylaldiminato ligand, K[2-(C6H5NCH)C4H3N], to afford the first examples of hybrid salicylaldiminato-ligated octahedral titanium complexes; the pre-catalysts give from very high to extremely high ethene polymerisation productivities when activated with MAO.
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