Synthesis of novel palladium OCN-pincer complexes: unprecedented sequential C(sp3)–H activation and aerobic oxidation in the reaction of N,N-dialkyl-3-[(N,N-dimethylamino)methyl]-2-iodoanilines with Pd2(dba)3

Literature Information

Publication Date 2005-04-15
DOI 10.1039/B502854J
Impact Factor 6.222
Authors

Daniel Solé, Lluís Vallverdú, Xavier Solans, Mercé Font-Bardia


View Original

Abstract

The reaction of N,N-dialkyl-3-[(N,N-dimethylamino)methyl]-2-iodoanilines with Pd2(dba)3 under O2 gives palladium OCN-pincer complexes by means of an unprecedented process that involves the formal aerobic oxidation of C(sp3)–H bonds at the α position of the aniline N atom.

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