A pyrimidine-like nickel(ii) DNA base pair
Literature Information
Christopher Switzer, Dongwon Shin
4-(2′-Pyridyl)-pyrimidinone deoxyriboside is synthesized and characterized as a DNA metallo base-pair; this novel nucleoside forms a self-pair in the presence of Ni(II) and stabilizes double helical DNA to the same extent as a G·C pair.
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