Regiospecific topochemical reactions controlled by trifluoromethyl directing groups

Literature Information

Publication Date 2004-11-29
DOI 10.1039/B413898H
Impact Factor 6.222
Authors

Jin Liu, Kelly Jo Boarman


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Abstract

A parallel, offset-stacked orientation was found in the crystal packing of E,E-1,4-di(o-trifluoromethyl)phenyl-1,3-butadiene. UV-irradiation of the powered crystalline sample resulted in a quantitative conversion to a single [2 + 2] cycloaddition product.

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