Sr11Ge4N6: a new nitride composed of [GeN2Sr7]4+ antiperovskite-type slabs and [Sr4Ge]4+ layers, separated by sheets of bent [GeIIN2]4− ions
Literature Information
Zoltán A. Gál, Simon J. Clarke
The layered nitride Sr11Ge4N6 contains Ge4− Zintl anions in both [Sr4Ge]4+ layers and [GeN2Sr7]4+ antiperovskite-type slabs which are separated by sheets of bent [GeIIN2]4− ions; the observed range of formal germanium oxidation states in nitrides thus extends between +4 and −4.
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