Sr11Ge4N6: a new nitride composed of [GeN2Sr7]4+ antiperovskite-type slabs and [Sr4Ge]4+ layers, separated by sheets of bent [GeIIN2]4− ions

Literature Information

Publication Date 2004-12-21
DOI 10.1039/B413534B
Impact Factor 6.222
Authors

Zoltán A. Gál, Simon J. Clarke


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Abstract

The layered nitride Sr11Ge4N6 contains Ge4− Zintl anions in both [Sr4Ge]4+ layers and [GeN2Sr7]4+ antiperovskite-type slabs which are separated by sheets of bent [GeIIN2]4− ions; the observed range of formal germanium oxidation states in nitrides thus extends between +4 and −4.

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