Unexpected oxidative C–C cleavage in the metallation of 2-substituted imidazolium salts to give N-heterocyclic carbene complexes
Literature Information
Anthony R. Chianese, Brian M. Zeglis, Robert H. Crabtree
Imidazolium salts blocked at C2 with methyl or benzyl groups unexpectedly react with silver oxide to give N-heterocyclic carbene complexes of silver via an oxidative carbon–carbon bond cleavage.
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