![1,1',1'',1'''-[Disulfanediylbis(carbonothioylnitrilo)]tetraethane structure](https://static.chemtradehub.com/structs/97-/97-77-8-f3e4.webp "1,1',1'',1'''-[Disulfanediylbis(carbonothioylnitrilo)]tetraethane structure")
1,1',1'',1'''-[Disulfanediylbis(carbonothioylnitrilo)]tetraethane
CAS Number:
97-77-8
Molecular Formula:
C10H20N2S4
Allylboration as a versatile tool for the in situ post-polymerization functionalization of 1,4-cis-poly(butadiene)
Literature Information
Publication Date
2016-09-23
DOI
10.1039/C6PY01388K
Impact Factor
5.582
Authors
Hannes Leicht, Steffen Huber, Inigo Göttker-Schnetmann, Stefan Mecking
View Original
Abstract
Allylboration is a versatile tool for the post-polymerization functionalization of poly(butadiene-co-[4,4,5,5-tetramethyl-2-(3-methyl-1,3-butadienyl)-1,3,2-dioxaborolane]). Polar functionalized aldehydes HC(O)C6H4(CH2)R (R = Br, NR2, PPh3, P(O)(OEt)2) react readily with the allyl boronic acid ester groups in the copolymer without interfering with the reactive double bonds in the polymer backbone. This provides access to stereoregular poly(butadiene) functionalized with a broad range of polar groups. Functionalization proceeds under polymerization conditions and therefore does not require a prior polymer work-up.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
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