Humidity sensitive properties of alkoxysilane-crosslinked polyelectrolyte using sol-gel process

Literature Information

Publication Date 2004-06-07
DOI 10.1039/B404334K
Impact Factor 4.616
Authors

Chil-Won Lee, Byoung-Koo Choi, Myoung-Seon Gong


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Abstract

New trialkoxysilyl group-containing copolymers for humidity-sensitive polyelectrolytes were prepared by copolymerization of [2-(methacryloyloxy)ethyl]trimethyl ammonium chloride (METAC), 3-(trimethoxysilyl)propyl methacrylate (TSPM) and 2-ethylhexyl acrylate (2-EHA). They were self-crosslinkable copolymers composed of different contents of METAC/TSPM/2-EHA = 4/1/5 and 4/2/4. The resistance varied from 107 to 103 Ω between 20% RH and 95% RH, which was required for a humidity sensor operating at ambient humidity. Temperature dependence, hysteresis, response time, water durability and long-term stability at high temperature and humidity were also measured and estimated.

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