Direct synthesis of hydrogen peroxide solution with palladium-loaded sulfonic acid polystyrene resins
Literature Information
Gema Blanco-Brieva, Encarnación Cano-Serrano, Jose M. Campos-Martin, Jose L. G. Fierro
Anchorage of PdII ions into mesoporous ion-exchange resins functionalized with sulfonic groups is highly effective for the direct synthesis of hydrogen peroxide using methanol as a solvent at 313 K. The high performance of these catalytic systems is due to the ability of sulfonic acid groups of the resin to interact and stabilize PdII ions without further reduction to metallic palladium, as revealed by photo-electron spectroscopy.
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