Direct synthesis of hydrogen peroxide solution with palladium-loaded sulfonic acid polystyrene resins

Literature Information

Publication Date 2004-04-22
DOI 10.1039/B402530J
Impact Factor 6.222
Authors

Gema Blanco-Brieva, Encarnación Cano-Serrano, Jose M. Campos-Martin, Jose L. G. Fierro


View Original

Abstract

Anchorage of PdII ions into mesoporous ion-exchange resins functionalized with sulfonic groups is highly effective for the direct synthesis of hydrogen peroxide using methanol as a solvent at 313 K. The high performance of these catalytic systems is due to the ability of sulfonic acid groups of the resin to interact and stabilize PdII ions without further reduction to metallic palladium, as revealed by photo-electron spectroscopy.

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