Self-catalyzing photoredox polymerization for recyclable polymer catalysts

Literature Information

Publication Date 2021-04-07
DOI 10.1039/D1PY00208B
Impact Factor 5.582
Authors

Jacob J. Lessard, Georg M. Scheutz, Angie B. Korpusik, Rebecca A. Olson, C. Adrian Figg, Brent S. Sumerlin


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Abstract

We describe a self-catalyzing photoredox polymerization system for the modular generation of macromolecular photocatalysts. Specifically, we designed a photoactive eosin Y-derived monomer that can induce photoelectron/energy transfer, while simultaneously partaking in reversible addition–fragmentation chain transfer polymerization as a monomer, affording polymer catalysts with tunable eosin Y incorporations.

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Polymer Chemistry
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