Porphyrin ring contraction: a one-pot reaction leading to divalent corroles
Literature Information
Christophe Jeandon, Romain Ruppert, Henry J. Callot
Reaction of nickel meso-tetraarylporphyrins with benzoic anhydride and tin tetrachloride, followed by air oxidation under basic conditions, results in ring contraction, yielding divalent corroles.
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Chemical Communications

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![1-oxaspiro[4.4]nonan-6-one structure 1-oxaspiro[4.4]nonan-6-one structure](https://static.chemtradehub.com/structs/134/134179-01-4-e051.webp)

