Porphyrin ring contraction: a one-pot reaction leading to divalent corroles

Literature Information

Publication Date 2004-04-02
DOI 10.1039/B400812J
Impact Factor 6.222
Authors

Christophe Jeandon, Romain Ruppert, Henry J. Callot


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Abstract

Reaction of nickel meso-tetraarylporphyrins with benzoic anhydride and tin tetrachloride, followed by air oxidation under basic conditions, results in ring contraction, yielding divalent corroles.

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