Evidence for C60 dimerisation in the fulleride [Cr(C9H12)2]+C60−
Literature Information
Andreas Hönnerscheid, Leo van Wüllen, Robert Dinnebier, Martin Jansen, Jürgen Rahmer, Michael Mehring
We report a detailed study of the structure, dynamics and electronic structure of the new fulleride [Cr(C9H12)2]+C60−. Using a variety of characterization tools including EPR, NMR, SQUID magnetic measurements and high resolution X-ray powder diffraction a spin pairing of the C60− spins with decreasing temperatures could be observed. Contrary to the observed phase transition of first order in the related compound [Cr(C6H9)2]+C60− the phase transition observed in the title compound is of higher order.
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