Evidence for C60 dimerisation in the fulleride [Cr(C9H12)2]+C60−

Literature Information

Publication Date 2004-03-18
DOI 10.1039/B317060H
Impact Factor 3.676
Authors

Andreas Hönnerscheid, Leo van Wüllen, Robert Dinnebier, Martin Jansen, Jürgen Rahmer, Michael Mehring


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Abstract

We report a detailed study of the structure, dynamics and electronic structure of the new fulleride [Cr(C9H12)2]+C60−. Using a variety of characterization tools including EPR, NMR, SQUID magnetic measurements and high resolution X-ray powder diffraction a spin pairing of the C60− spins with decreasing temperatures could be observed. Contrary to the observed phase transition of first order in the related compound [Cr(C6H9)2]+C60− the phase transition observed in the title compound is of higher order.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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