Eu(iii)–cyclen–phen conjugate as a luminescent copper sensor: the formation of mixed polymetallic macrocyclic complexes in water

Literature Information

Publication Date 2004-03-03
DOI 10.1039/B316176E
Impact Factor 6.222
Authors

Thorfinnur Gunnlaugsson, Joseph P. Leonard, Katell Sénéchal, Andrew J. Harte


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Abstract

The cationic cyclen based Eu(III)–phen conjugated 1·Eu was synthesised as a chemosensor for Cu(II), where the recognition in water at pH 7.4 gave rise to quenching of the Eu(III) luminescence and the formation of tetranuclear polymetallic Cu(II)–Eu(III) macrocyclic complexes in solution where Cu(II) was bound by three 1·Eu conjugates.

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Contents list

Front/Back Matter

DOI: 10.1039/C4CP90152E

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Source Journal

Chemical Communications

Chemical Communications
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ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

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